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Abstract
Chloromethylboryl-N-tosylhydrazone (CMBT) has been synthesized as a reagent to generate a diverse range of molecular skeletons. CMBT can undergo a series of transformations involving nucleophilic substitution of the chloride, coupling of the N-tosylhydrazones, follwed by boryl group functionalization. We further demonstrated that this CMBT reagent could enable a diverisity-oriented synthesis.
Supplementary materials
Title
Supplementary Information
Description
Electronic Supplementary Information (ESI) available: CCDC 2257615 (for CMBT) and CCDC 2257609 (for 4a). For experimental procedures, spectroscopic data for compounds, and crystallographic data in CIF
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