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Heteroleptic Tetravalent š¯›½-Diketonate Molybdenum Complexes as Highly Active Catalysts for Allylic Substitution Reactions

27 February 2023, Version 1
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

The synthesis and characterization of a series of Mo(IV) bis-š¯›½-diketonate (^(R)diket, R = Me, tBu, Ph) dichloride (RMo^(IV)Cl_2) and bistriflate (^(R)Mo^(IV)(OTf)_2) complexes are reported. All complexes are characterized in solid and solution state by XRD and 1H NMR spectroscopy. We demonstrate that the bistriflate complexes constitute highly active catalysts for allylic substitution reactions.

Keywords

molybdenum
allylic substitution
diketonate

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Version History

Feb 27, 2023 Version 1

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The content is available under CC BY 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv-2023-rlbk8
D O I: 10.26434/chemrxiv-2023-rlbk8 [opens in a new tab]

Authorā€™s competing interest statement

The author(s) have declared they have no conflict of interest with regard to this content

Ethics

The author(s) have declared ethics committee/IRB approval is not relevant to this content

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