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2,6-Bis[[bis(1,1-dimethylethyl)phosphino-κP]methyl]phenyl-κC]chlorohydro(phenylphosphine)iridium

26 May 2022, Version 1
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

The molecular structure of an iridium complex featuring a phenylphosphine ligand is described. Reaction of (POCOP)IrHCl (1, POCOP = 2,6-(tBu2PO)2C6H3–) with phenylphosphine gives (POC-OP)IrHCl(PH2Ph) (2) under mild conditions. Structural features are consistent with a classic pseudo-octahedral iridium compound with three neutral phosphine donors. Compound 1 is un-reactive at elevated temperature and unreactive toward excess phenylphosphine under condi-tions sampled.

Supplementary materials

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Supporting information
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spectra and label scheme
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Checkcif report
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IUCr report on uploaded data
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Version History

May 26, 2022 Version 1

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DOI

10.26434/chemrxiv-2022-zzfqs
D O I: 10.26434/chemrxiv-2022-zzfqs [opens in a new tab]

Funding

National Science Foundation
CHE-2101766
National Science Foundation
CHE-1565658

Author’s competing interest statement

The author(s) have declared they have no conflict of interest with regard to this content

Ethics

The author(s) have declared ethics committee/IRB approval is not relevant to this content

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